Simple interest (SI) is charged on the original principal every year. Compound interest (CI), with annual compounding, is charged on the principal plus all interest added so far. For the first year the two are identical. From the second year on, CI also earns interest on interest, and the gap between CI and SI is exactly that interest on interest.
Questions on the CI − SI difference can be solved by computing both values in full, but the two short formulas below are faster and, once you see where they come from, easy to rebuild.