A die is a cube with six faces. Each face touches four others, called its adjacent faces, and is directly opposite the remaining one. At any moment you can see at most three faces: the top, the front and one side. Dice questions show you one or more such positions and ask which faces are opposite each other.
Since each face touches 6 − 2 = 4 others, two faces that are ever seen together in one position can never be opposite. That simple fact is the basis of every rule below.
A die can rest in 6 × 4 = 24 different orientations, so do not rely on picturing the rotation in your head. Use the rules instead.
In this page every position is written as top, front and right face, in that order, as you would see them in a printed figure.